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Chloramine and Your Aquarium

One problem with using chlorine to treat water is that it breaks down relatively quickly. Another concern with the use of chlorine is that it can combine with certain organics (that may or may not be present in your water) forming trihalomethanes, a family of carcinogens. Consequently, many water companies have switched from using chlorine to using chloramine. Chloramine, a compound containing both chlorine and ammonia, is much more stable than chlorine.

test tubes, chemistry, glass

Chloramine poses two significant headaches for aquarists. First, chlorine-neutralizing chemicals such as sodium thiosulfate only neutralize the chlorine portion of chloramine, neglecting an even bigger problem: deadly ammonia. The consequences can be devastating to fish. Although a tank’s biological filter will (eventually) convert the ammonia to nitrate, the time it takes to do so may be longer than what your fish can tolerate.

The second problem relates to water changes. One of the primary reasons for doing regular water changes is to remove nitrates that build up. If your replacement tap water contains ammonia, you’ll be putting nitrogen right back into your tank and it will be impossible to reduce the nitrates below the concentration in your tap water. Fortunately, tap water concentrations are relatively low (1 or 2 ppm); you are more likely to have a much higher concentration of nitrate in your tank.
Chloramine can be safely neutralized through such products as Amquel, which neutralize both the ammonia and chlorine portions of the chloramine molecules. The neutralized ammonia will still be converted to nitrates via a biological filter.

Another method for neutralizing chloramine is to age it while simultaneously performing biological filtration. For example, get an appropriately-sized (plastic) garbage can, fill it with tap water, dechlorinate it with sodium thiosulfate, and then connect an established biological filter to it. Just as in your tank, the bio filter will convert the ammonia to nitrate, after which it can safely be added to your tank. Note: you must add sodium thiosulfate to neutralize the chlorine; otherwise, the chloramine will kill the bacteria in your biological filter.

Alternatively, the ammonia can removed by filtering the water through zeolite or carbon before adding it to your tank. [Note: folks report mixed success with this. If you have concrete (positive or negative) experience to report, please notify the FAQ maintainers.

Source:  users.cs.duke.edu/~narten/faq/chemistry.html